华中科技大学化学与化工学院 华中科技大学化学与化工学院

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姓 名: 顾彦龙   Gu Yanlong
出生年月:1978-02
学历: 博士研究生
职称: 教授
专业方向:均相催化、绿色合成
电 话:15907153484
Email:klgyl@hust.edu.cn
个人主页:https://www.researchgate.net/profile/Yanlong_Gu

教育与研究经历

2008/10-现在,华中科技大学教授,教授

2006/10-2008/07,法国普瓦捷大学(导师:Francois Jerome教授),博士后,从事生物质资源综合利用研究

2005/08-2006/09,日本东京大学(导师:Shū Kobayashi教授),博士后,从事水相催化研究

1999/09-2005/06,中科院兰化所(导师:邓友全研究员),博士研究生,从事离子液体研究

1995/09-1999/07,内蒙古大学,化学系,本科

研究领域与兴趣

均相酸碱催化:以构建高效、可回收催化体系为目标,借助多相、均相酸碱催化剂研究生物质高值化转化、精细化学品合成等重要反应。

绿色合成化学:围绕环境友好介质、原子经济反应和生物质利用等绿色化学研究主题开展催化与合成化学研究。

教学情况

本科生课程:绿色化工、物理化学实验、有机化学

研究生课程:绿色化学前沿(全英语)

承担项目与课题

国家自然科学基金面上项目,21373093、基于反应控制理念的均相催化与合成体系多样化设计研究、2014/01-2017/1284万元、主持。

国家自然科学基金面上项目,21173089、基于取代二氢吡喃的分子催化基础研究、2012/01-2015/12、62万元、主持。

教育部新世纪优秀人才计划,NCET-10-0383,2010/01-2014/12、50万元、主持。

国家自然科学基金青年基金、20903042、担载离子液体协助固体催化剂体系研究、2010/01-2012/12、20万元、主持。

国家自然科学基金国际合作交流项目,21111130192、附加离子液体协助的固体催化剂催化纤维素转化研究、2011/02-2011/12、1.5万、主持。 

学术兼职

中国化学会绿色化学专业委员会委员

中国化工学会离子液体专业委员会委员

Current Organic Chemistry编委、亚洲区编辑

《过程工程学报》编委会委员

《催化学报》青年编委

代表性成果

2017年

1. Zhifang Jia, Kewei Wang, Bien Tan,* and Yanlong Gu,* Ruthenium Complexes Immobilized on Functionalized Knitted HypercrosslinkedPolymers as Efficient and Recyclable Catalysts for Organic Transformations, Adv.Synth. Catal., 2017, 359, 78–88.

2. Palanisamy Ravichandiran, Bingbing Lai, Yanlong Gu,* Aldo-X Bifunctional Building Blocks for the Synthesis of Heterocycles, Chem. Rec., 2017, 17, 142–183 (cover page paper).

3. Wenbo Huang, Changhui Liu,* and Yanlong Gu,* Auto-tandem catalysis-induced facile synthesis of trisubstituted furans through domino acid-acid-catalyzed reaction of aliphatic aldehydes and 1,3-dicarbonyl compounds by using NBS as oxidant, Adv. Synth. Catal., 2017, 359, 1811–1818 (cover page paper).

4. Kewei Wang, Zhifang Jia, Xuekang Yang, Ling Wang, Yanlong Gu,* Bien Tan,* Acid and base coexisted heterogeneous catalysts supported on hypercrosslinked polymers for one-pot cascade reactions, J. Catal., 2017, 348, 168–176.

5. Zhifang Jia, Kewei Wang, Bien Tan,* Yanlong Gu,* Hollow hypercrosslinked nanospheres with acid and base sites as efficient and water-stable catalysts for one-pot tandem reactions, ACS Catal., 2017, DOI: 10.1021/acscatal.6b03631.

2016年:

1. Changhui Liu, Li Zhou, Wenbo Huang, Man Wang, and Yanlong Gu,* Synthesis of Furans and Pyrroles from 2-Alkoxy-2,3-dihydrofurans Through a Nucleophilic Substitution-Triggered Heteroaromatization, Adv. Synth. Catal., 2016, 358, 900–918.

2. Changhui Liu, Li Zhou, Dan Jiang, and Yanlong Gu,* Multicomponent Reactions of Aldo-X Bifunctional Reagent a-Oxoketene Dithioacetals and Indoles or Amines: Divergent Synthesis of Dihydrocoumarins, Quinolines, Furans, and Pyrroles, Asian J. Org. Chem.2016, 5, 367–372 (ESI highly cited paper).

3. Li You, Xiao-Fei Ren, YunWang, Zhong-Hua Ma,* Yanlong Gu,* and Jing-Zhong Ma, “Release and Catch” Effect of Perfluoroalkylsulfonylimide-Functionalized Imidazole/Pyridine on Brønsted Acids in Organic Systems, ChemCatChem, 2016, 8, 3394–3401.

4. Zhifang Jia, Kewei Wang, Tao Li, Bien Tan* and Yanlong Gu,* Functionalized hypercrosslinked polymers with knitted N-heterocyclic carbene–copper complexes as efficient and recyclable catalysts for organic transformations, Catal. Sci. Technol., 2016, 6, 4345–4355.

5. Bingbing Lai, Zhipeng Huang, Zhifang Jia, Rongxian Bai* and Yanlong Gu,* Silica-supported metal acetylacetonate catalysts with a robust and flexible linker constructed by using 2-butoxy-3,4-dihydropyrans as dual anchoring reagents and ligand donors†, Catal. Sci. Technol., 2016, 6, 1810–1820.

6. Lijun Min, Bin Pan, and Yanlong Gu,* Synthesis of Quinoline-Fused 1-Benzazepines through a MannichType Reaction of a C,N-Bisnucleophile Generated from 2-Aminobenzaldehyde and 2-Methylindole,Org. Lett.2016, 18, 364–367.

7. Amir Taheri, Bingbing Lai, Jing Yang,* Juan Zhang,* Yanlong Gu,* Facile synthesis of densely substituted chroman derivatives through Brønsted acid ionic liquid catalyzed three-component reactions of aromatic aldehydes, 1,1-diarylethylenes and nucleophiles, Tetrahedron2016, 72, 479–488.

8. Rongxian Bai, Jian Yang, Lijun Min, Changhui Liu, Fengtian Wu and Yanlong Gu,* Facile synthesis of 3,4-fused tricyclic indoles with a seven-membered ring through a three-component reaction of 4-hydroxyindole, aldehyde, and malonodinitrile or ethyl cyanoacetate, Tetrahedron, 2016, 72, 2170–2177.

9. Changhui Liu, Li Zhou, Wenbo Huang, Man Wang, Yanlong Gu,* Synthesis of dihydrocarbazoles via (4+2) annulation of donor-acceptor cyclopropanes to indoles, Tetrahedron2016, 72, 563–570.

10. Fengtian Wu, Rongxian Bai,* and Yanlong Gu,* Synthesis of Benzofurans from Ketones and 1,4-Benzoquinones, Adv. Synth. Catal., 2016, 358, 2307–2316.

11. Changhui Liu, Wenbo Huang, Man Wang, Bin Pan, Yanlong Gu, Expedient Synthesis of Substituted Benzoheterocycles using 2-Butoxy-2,3-dihydrofurans as [4+2] Benzannulation Reagent, Adv. Synth. Catal., 2016, 358, 2260–2266 (cover page paper).

12. Changhui Liu, Bin Pan, Yanlong Gu,* Lewis base‐assisted Lewis acid‐catalyzed selective alkene formation via alcohol dehydration and synthesis of 2‐cinnamyl‐1,3‐dicarbonyl compounds from 2‐aryl‐3,4‐dihydropyrans, Chin. J. Catal., 2016, 37, 979–986 (Invited).

2015年:

1. Rongxian Bai, Ping Liu, Jian Yang, Changhui Liu, and Yanlong Gu,*Facile Synthesis of 2-Aminothiophenes Using NaAlO2 as an Eco-Effective and Recyclable Catalyst, ACS Sustainable Chem. Eng., 2015, 3, 1292–1297.

2. Jie Yang, Karine De Oliveira Vigier, Yanlong Gu,*and Francois Jérôme, * Catalytic Dehydration of Carbohydrates Suspended in Organic Solvents Promoted by AlCl3/SiO2 Coated with Choline Chloride, ChemSusChem2015, 8, 269–274.

3. Kexing Zeng, Zhipeng Huang, Jie Yang, Yanlong Gu,* Silica-supported policresulen as a solid acid catalyst for organic reactions, Chin. J. Catal., 2015, 36. 1606–1613 (Invited).

4. Changhui Liu, Amir Taheri, Bingbing Lai and Yanlong Gu,* Synergistic catalysis-induced ring-opening reactions of 2-substituted 3,4-dihydropyrans withα-oxoketene dithioacetals†, Catal. Sci. Technol., 2015, 5, 234–245 (hot paper).

5. Amir Taheri, Bingbing Lai, Cheng Cheng and Yanlong Gu,* Brønsted acid ionic liquid-catalyzed reductive Friedel–Crafts alkylation of indoles and cyclic ketones without using an external reductant†, Green Chem., 2015, 17, 812–818 (ESI highly cited paper).

6. Yizhu Lei, Linjuan Wu, Xuefeng Zhang, Hui Mei, Yanlong Gu,* Guangxing Li,* Palladium supported on triphenylphosphine functionalized porous organic polymer: A highly active and recyclable  catalyst for alkoxycarbonylation of aryl iodides, J. Mol. Catal. A: Chem., 2015, 398, 164–169.

7. Cheng Cheng, Changhui Liu, Yanlong Gu,* One-pot three-component reactions of methyl ketones, phenols and a nucleophile: an expedient way to synthesize densely substituted benzofurans, Tetrahedron, 2015, 71, 8009-8017.

2014年

1. Changhui Liu and Yanlong Gu,* Synthesis of densely substituted 1,3-butadienes through acid-catalyzed alkenylations of a-oxoketene dithioacetals with aldehydes, J. Org. Chem. 2014, 79(20), 9619–9627.

2. Jing Yang, Shaohuan Sun, Biaozhang, Juan Zhang,* and Yanlong Gu,* 2-Alkoxy-3,4-dihydropyrans as modular substrates to construct polyheterocycles by reacting with NH2-containing bisnucleophiles,Tetrahedron, 201470, 9214–9223.

3. Dan Jiang,Xiaojuan Pan,Minghao Li,and Yanlong Gu,* 2-Methylindole as an Indicative Nucleophile for Developing a Three-Component Reaction of Aldehyde with Two Different Nucleophiles, ACS Comb. Sci., 2014, 16, 287–292.

4. Minghao Li, Amir Taheri, Meng Liu, Shaohuan Sun, and Yanlong Gu,* Three-Component Reactions of Aromatic Aldehydes and Two Different Nucleophiles and their Leaving Ability-Determined Downstream Conversions of the Products, Adv. Synth. Catal., 2014, 356, 537–556.

5. Xiaojuan Pan, Minghao Li, and Yanlong Gu,* Fe(OTf)3-catalyzed a-benzylation of aryl methyl ketones with electrophilic secondary and aryl alcohols, Chem. Asian J., 2014, 9, 268–274.

6. Shaohuan Sun, Rongxian Bai,* and Yanlong Gu,* From waste biomass to solid support: lignosulfonate as a cost-effective and renewable supporting material for catalysis, Chem. Eur. J., 2014, 20, 549–558.

7. Amir Taheri, Xiaojuan Pan, Changhui Liu, and Yanlong Gu,* Brøsted acid ionic liquid as a solvent-conserving catalyst for organic reactions, ChemSusChem, 2014, 7, 2094–2098.

8. Amir Taheri, Changhui Liu, Bingbing Lai, Cheng Cheng, Xiaojuan Pan and Yanlong Gu,* Brønsted acid ionic liquid catalyzed facile synthesis of 3-vinylindoles through direct C3 alkenylation of indoles with simple ketones, Green Chem., 2014, 16, 3715–3719.

9. Shaohuan Sun, Cheng Cheng, Jian Yan, Amir Taheri, Dan Jiang, Biao Zhang, and Yanlong Gu,* Synthesis of tetrahydropyridine derivatives through a modular assembly reaction using 3,4-dihydropyran as dual substrate and template, Org. Lett., 2014, 16, 4520–4523.

10.Binshen Wang, Sijuan Yang, Lijun Min, Yanlong Gu,* Yongya Zhang, Xiaopei Wu, Lifeng Zhang, Elnazeer H. M. Elageed, Shi Wu, and Guohua Gao,* Eco-efficient synthesis of cyclic carbamates/dithiocarbonimidates from cyclic carbonates/trithiocarbonate and aromatic amines catalyzed by ionic liquid BmimOAc, Adv. Synth. Catal., 2014, 356, 3125–3134.

2013年以前论文见个人主页。

获奖与荣誉

2015年 获得华中科技大学十佳青年教工

2014年-2016年(爱斯维尔)中国化学工程领域高被引学者

2012年 获得中国化学会催化专业委员会“催化新秀”奖

2012年 获得华中科技大学青年五四奖章

2010年 获得武汉市青年科技奖

2009年 入选教育部“新世纪优秀人才支持计划”

2008年 获得楚天学者支持计划“楚天学子”

更多信息请浏览个人(或课题组)主页:https://www.researchgate.net/profile/Yanlong_Gu