华中科技大学化学与化工学院 华中科技大学化学与化工学院

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姓 名: 尹国川   gyin
出生年月:1968-08
学历: 博士
职称: 教授
专业方向:催化化学
电 话:15997442682
Email:gyin@hust.edu.cn
个人主页:http://com.chem.hust.edu.cn/

教育与研究经历

 

教育

1986-1990     学士学位,浙江大学化学系

1992-1995      硕士学位,中国科学院大连化学物理研究所

1995-1998      博士学位,中国科学院大连化学物理研究所(导师:奚祖威研究员)

 

工作经历

2008-              华中科技大学化学化工学院教授

2001-2007       美国堪萨斯大学环境友好催化中心博士后

1999-2001      日本学术振兴会研究员(JSPS),日本九州大学

1998-1999      南京大学化学化工学院教师

1990-1992      四川省芒硝矿助理工程师

研究领域与兴趣

催化化学中的催化氧化领域,1)生物酶催化氧化机理的模型研究,2)催化助剂对氧化催化剂的调控机理研究,3)Pd(II)/路易斯酸催化C-H键活化与官能团化化研究,4)基于生物质糠醛的催化转化研究,5)工业及生活废水降解的氧化催化剂研制。

教学情况

本科教学: 物理化学,催化化学

研究生教学: 催化化学

承担项目与课题

 1. 国家自然科学基金:“高价态过渡金属氧与氢氧物种在氧化过程中的立体选择性差异及相关问题”,2010-2012 (No. 20973069);

2. 国家自然科学基金:“含刚性交叉桥联大环配体钌配合物的合成及在氧化基础研究中的应用”,2010-2012 (No. 21273086);

3.国家自然科学基金:“基于路易斯酸提升过渡金属活化C-H键能力的催化剂设计与应用”,2016-2019 (No. 21573082);

3. 教育部博士点基金(博导类):“路易斯酸提升的过渡金属催化惰性C-H键活化与选择氧化剂相关研究”,2013-2016(No. 20130142110034)

国际邀请报告

1.The International Conference on Hydrogen Atom Transfer, Rome, Italy, 2014.6.22-26;

2.The 2015 Metals in Biology Gordon Research Conferences, Ventura, California, USA, 2015.1. 25-30;

3.The 48th General Assembly Meeting of the International Union of Pure and Applied Chemistry (IUPAC-2015), August,  2015, Busan, Korea;

4.ChemComm Symposia on Molecular Design and Analysis, August, 2015, Korea;

5.The International Chemical Congress of Pacific Basin Societies (PacifiChem-2015), December, 2015, Hawaii, USA ;

6.The 9th International Conference on Porphyrins and Phthalocyanines (ICPP-9), July, 2016, Nanjing.

7.The 4th International Symposium for Young Chemists on Stimuli-Responsive Chemical Species for the Creation of Functional Molecules, 12-13 Dec., 2016, Osaka, Japan.

学术兼职

1. 湖北省化学化工学会理事

2. E-Journal of Chemistry编委

代表性成果

1.Zhang, Jisheng; Yang, Hang; Sun, Tingting; Chen, Zhuqi; Yin, Guochuan*,Nonredox Metal-?Ions-?Enhanced Dioxygen Activation by Oxidovanadium(IV) Complexes toward Hydrogen Atom Abstraction, Inorg. Chem. 2017, 56, 834-844.

2.Sicheng Zhang, Zhuqi Chen, Shuhao Qin, Chenling Lou, Ahmed M. Senan, Rongzhen Liao*,Guochuan Yin*, Non-redox metal ions promoted oxidative coupling of indoles with olefins by Pd(OAc)2 catalyst through dioxygen activation: Experimental results with DFT calculations, Org. Biomol. Chem. 2016, 14, 4146 – 4157.

3.Shuhao Qin, Lei Dong, Zhuqi Chen, Sicheng Zhang and Guochuan Yin*,Non-redox metal ions can promote Wacker-type oxidations even better than copper(II) : a new opportunity in catalyst design, Dalton Trans. 2015, 44, 17508 – 17515.

4.Zhuqi Chen, Ling Yang, Cholho Choe, Zhanao Lv, Guochuan Yin*, Non-redox Metal Ions Promoted Oxygen Transfer by a Non-heme Manganese Catalyst”,Chem. Commun. 2015, 51, 1874-1877.

5.Zhuqi Chen and Yin, Guochuan*, The reactivity of the active metal oxo and hydroxo intermediates and its implications in oxidations, Chem. Soc. Rev. 2015, 44 (5), 1083-1100.

6.Guochuan Yin*,Understanding the Oxidative Relationships of the Metal Oxo, Hydroxo and Hydroperoxide Intermediates with Manganese(IV) Complex Having Bridged Cyclam: Correlation of the Physicochemical Properties with Reactivity, Acc. Chem. Res. 2013, 46,483-492.

7.Zhou, Li; Song, Wei; Chen, Zhuqi; Guochuan Yin*, Degradation of Organic Pollutants in Wastewater by Bicarbonate-Activated Hydrogen Peroxide with a Supported Cobalt Catalyst, Environ. Sci. & Technol. 2013, 47, 3833-3839.

8.Huajun Guo, Guochuan Yin*, Catalytic Aerobic Oxidation of Renewable Furfural with Phosphomolybdic Acid Catalyst: an Alternative Route to Maleic Acid, J. Phys. Chem., C, 2011, 115, 17516-17522.

9.Song Shi, Yujuan Wang, Aihua Xu, Huajun Wang, Dajian Zhu, Suparna Baksi Roy, Timothy A. Jackson, Daryle H Busch, Guochuan Yin*, Distinct Reactivity Differences of Metal Oxo and Its Corresponding Hydroxo Moieties in Oxidations: Implications from a Manganese(IV) Complex Having Dihydroxide Ligand, Angew, Chem. Intl. Ed. 2011, 50, 7321-7324.

10.Guochuan Yin, Andrew M. Danby, David Kitko, John D. Carter, William M. Scheper and Daryle H. Busch,Oxidative Reactivity Difference Between the Metal Oxo and Metal Hydroxo Moieties: pH Dependent Hydrogen Abstraction by a Manganese(IV) Complex Having Two Hydroxide Ligands, J. Am. Chem. Soc.2008, 130,16245-16253.

11. Guochuan Yin, Andrew M. Danby, David Kitko, John Carter, William M. Scheper and Daryle H. Busch, Understanding the Selectivity of a Moderate Oxidation Catalyst:Hydrogen Abstraction by a Fully Characterized, Activated Catalyst, the Robust Dihydroxo Manganese (IV) Complex of a Bridged Cyclam,J. Am. Chem. Soc. 2007, 129, 1512-1513.

12. Guochuan Yin, Maria Buchalova, Andrew M Danby, Chris M Perkins, David Kitko, John D Carter, William M Scheper, Daryle H Busch, Olefin Oxygenation by the Hydroperoxide Adduct of a Nonheme Manganese(IV) Complex: Epoxidations by a Metallo-Peracid Produces Gentle Selective Oxidations,  J. Am. Chem. Soc. 2005, 127, 17170-17171.

获奖与荣誉

1. 2009年受聘楚天学者特聘教授

2. 2013年获评校“三育人积极分子”

更多信息请浏览个人(或课题组)主页:http://com.chem.hust.edu.cn/

更多信息请浏览个人(或课题组)主页:http://com.chem.hust.edu.cn/